Metal- catalysed Addition of β-Dicarbonyl Compounds to the Nitrile Carbon of Benzoyl Cyanide. Synthesis of 1-Amino-1-benzoyl-2,2-diacylethenes

DOI: 10.1039/c39840001593

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1593 - 1594 (1984)

Update date:2022-09-26

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Authors:

Basato, Marino

Corain, Benedetto

Cofler, Marino

Veronese, Augusto C.

Zanotti, Guiseppe

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Article abstract of DOI:10.1039/c39840001593

The complex (Hacac=pentane-2,4-dione) selectively catalyses addition of the intercarbonylic carbon atom of β-diketones to the cyano group of benzoyl cyanide, whereas usual basic organic catalysts lead to attack on the carbonyl carbon atom with

Full text of DOI:10.1039/c39840001593

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