95580-70-4

Upstream product

• 626-35-7 nitroacetic acid ethyl ester 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 

Downstream Products

• 608525-50-4 3-O-benzyl-1,2-di-O-tert-butyldimethylsilyl-4-O-ethoxycarbonyl-6-deoxy-6-nitro-β-D-glucopyranose 
• 95580-36-2 6-Acetamido-3-O-benzyl-6-desoxy-1,2,4,7-tetra-O-acetyl-L-glycero-β-D-gluco-heptopyranose 
• 95580-35-1 6-Acetamido-3-O-benzyl-6-desoxy-1,2,4,7-tetra-O-acetyl-L-glycero-α-D-gluco-heptopyranose 
• 95580-74-8 Ethyl-6-acetamido-5-O-acetyl-3-O-benzyl-6-desoxy-1,2-O-isopropyliden-L-glycero-α-D-gluco-heptofuranuronat 
• 95580-37-3 6-Acetamido-3-O-benzyl-5,7-O-benzyliden-6-desoxy-1,2-O-isopropyliden-L-glycero-α-D-gluco-heptofuranose 
• 95580-88-4 6-Acetamido-3-O-benzyl-6-desoxy-1,2-O-isopropyliden-L-glycero-α-D-gluco-heptofuranose 
• 95580-80-6 5-<(Acetoxyethyl)(acetyl)amino>-3-O-benzyl-5-desoxy-1,2-O-isopropyliden-α-D-xylofuranosid 
• 95580-78-2 5--3-O-benzyl-5-desoxy-1,2-O-isopropyliden-α-D-xylofuranosid 
• 95580-79-3 3-O-Benzyl-5-desoxy-1,2-O-isopropyliden-5-<(hydroxyethyl)amino>-α-D-xylofuranosid 
• 95580-71-5 Ethyl-6-acetamido-3-O-benzyl-6-desoxy-1,2-O-isopropyliden-D-glycero-α-D-gluco-heptofuranuronat 
• 95580-73-7 Ethyl-6-acetamido-3-O-benzyl-6-desoxy-1,2-O-isopropyliden-L-glycero-α-D-gluco-heptofuranuronat 
• 95580-72-6 Ethyl-6-acetamido-5-O-acetyl-3-O-benzyl-6-desoxy-1,2-O-isopropyliden-D-glycero-α-D-gluco-heptofuranuronat 

Relevant academic research and scientific papers

Synthesis of polyhydroxylated α-nitrocyclohexane carboxylic acids derived from D-glucose: A striking case of racemization

The first total synthesis of polyhydroxylated α-nitrocyclohexane carboxylic acids from sugars is reported. A salient aspect of the synthesis is an unexpected Henry-mediated racemization of this new class of highly functionalized cyclohexanes.

Two new examples of the rare C→O migration of ethoxycarbonyl groups

Two new examples of a carbon→oxygen ethoxycarbonyl group shift are described. Treatment of 3-ethoxycarbonylnitromethyl-1,2-O-isopropylidene-6-O-p-toluenesulfonyl- α-D-allofuranose (4) with Bu4NF leads to a rearrangement to 5-O-ethoxycarbonyl-1,