95602-16-7

Upstream product

• 18940-21-1 5,5-dimethyl-3-(phenylamino)cyclohex-2-en-1-one 
• 74-88-4 methyl iodide 
• 62-53-3 aniline 
• 126-81-8 dimedone 
• 35162-34-6 N-methyl-3,4-dimethoxyaniline 

Downstream Products

• 701-58-6 5,5-dimethyl-3-methylamino-2-cyclohexenone 
• 95602-19-0 N-1-(5,5-dimethylcyclohex-1-en-3-one)-1,1,2-trimethoxy-2,5-cyclohexadien-4-imine 

Relevant academic research and scientific papers

OXIDATIVE CYCLIZATION OF 3-ANILINO-CYCLOHEX-2-ENONES TO TETRAHYDROCARBAZOLES

3-Anilino-cyclohex-2-enones 1a-1c are prepared from anilines and 5,5-dimethyl-1,3-cyclohexanedione.Anodic oxidation of 1a affords the p-benzoquinone monoimine dimethyl acetal 4, that is cyclized with CF3CO2H to the tetrahydrocarbazole 6.Lead tetraacetate

ANODIC INTRAMOLECULAR ARYLATION OF ENAMINONES

N-Benzyl- and β-phenethyl-enaminones are cyclized at the anode to isoquinolines and benzazepines.