35162-34-6

Basic information

• Product Name: 3,4-dimethoxy-N-methylaniline
• Synonyms: 3,4-dimethoxy-N-methylaniline
• CAS NO: 35162-34-6
• Molecular Formula: C₉H₁₃NO₂
• Molecular Weight: 167.20502
• Mol File: 35162-34-6.mol
• Article Data: 26

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,4-dimethoxy-N-methylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-dimethoxy-N-methylaniline(35162-34-6)
• EPA Substance Registry System: 3,4-dimethoxy-N-methylaniline(35162-34-6)

Safety Data

• Hazardous Substances Data: 35162-34-6(Hazardous Substances Data)

Upstream product

• 881-70-9 3',4'-dimethoxyacetanilide 
• 6315-89-5 3,4-dimethoxyaniline 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 40926-90-7 3,4-dimethoxybenzoyl azide 
• 331435-18-8 N-(3,4-dimethoxyphenyl)-2-nitrobenzenesulfonamide 
• 77-78-1 dimethyl sulfate 
• 91-16-7 1,2-dimethoxybenzene 
• 25370-97-2 O-(p-toluenesulfonyl)-N-methylhydroxylamine 
• 50-00-0 formaldehyd 
• 1643864-41-8 C₁₄H₂₁NO₄ 
• 102421-43-2 N-((1,1-dimethylethyl)oxycarbonyl)-3,4-dimethoxyaniline 
• 686280-14-8 N-(3,4-dimethoxyphenyl)-N-methylformamide 
• 93-07-2 Veratric acid 

Downstream Products

• 216167-39-4 6-[(3,4-Dimethoxy-phenyl)-methyl-amino]-3-nitro-pyridine-2-carbonitrile 
• 145511-01-9 1-(4,5-Dimethoxy-2-dimethylaminobenzyl)-2-naphthol 
• 1134672-06-2 N-methyl-N-(4,4,4-trifluoroacetoacetyl)-3,4-dimethoxyanilide 
• 1404300-76-0 (N-(3,4-dimethoxyphenyl)-Nmethylacridin-9-amine) 
• 1174342-59-6 6,7-dimethoxy-1-methyl-4-phenylquinolin-2-one 
• 145510-99-2 1-(2-Methylamino-4,5-dimethoxybenzyl)-2-naphthol 
• 95602-16-7 3-(N-methyl-3,4-dimethoxyanilino)-5,5-dimethylcyclohex-2-enone 

Relevant articles and documents

-

-

Erratum: Cu-Catalyzed Three-Component Carboamination of Alkenes (J. Am. Chem. Soc. (2018) 140:1 (58?61) DOI: 10.1021/jacs.7b10529)

Pages 59 and 60. We have identified an error in the structural analysis of compounds presented in our publication detailing. (Table presented).

Synthesis of: N -methylated amines from acyl azides using methanol

The transformation of acyl azide derivatives into N-methylamines was developed using methanol as the C1 source via the one-pot Curtius rearrangement and borrowing hydrogen methodology. Following this protocol, various functionalised N-methylated amines were synthesized using the (NNN)Ru(ii) complex from carboxylic acids via an acyl azide intermediate. Several kinetic studies and DFT calculations were carried out to support the mechanism and also to determine the role of the Ru(ii) complex and base in this transformation.