95605-15-5Relevant academic research and scientific papers
Trimethylorthoformate: A Mild and Effective Dehydrating Reagent for Solution and Solid Phase Imine Formation.
Look, Gary C.,Murphy, Martin M.,Campbell, David A.,Gallop, Mark A.
, p. 2937 - 2940 (1995)
Trimethylorthoformate has been found to be an effective dehydrating solvent for the formation of imines, both in the solid phase as well as solution phase.
A convenient procedure for the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides and alkenes
Alemparte, Carlos,Blay, Gonzalo,Jorgensen, Karl Anker
, p. 4569 - 4572 (2007/10/03)
(Chemical Equation Presented) Silver fluoride and cinchona alkaloids catalyze the diastereo- and enantioselective 1,3-dipolar cycloaddition between azomethine ylides, generated from N-alkylideneglycine esters, and acrylates to give the corresponding endo-adducts. Azomethine ylides derived from aromatic and aliphatic aldehydes react in a highly diastereoselective reaction with good yields and enantioselectivities of the substituted pyrrolidines.
