956346-88-6

Basic information

• Product Name: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(NH₂C₆H₅)
• CAS NO: 956346-88-6
• Molecular Weight: 722.643
• Mol File: 956346-88-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(NH₂C₆H₅)(CAS DataBase Reference)
• NIST Chemistry Reference: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(NH₂C₆H₅)(956346-88-6)
• EPA Substance Registry System: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(NH₂C₆H₅)(956346-88-6)

Safety Data

• Hazardous Substances Data: 956346-88-6(Hazardous Substances Data)

Upstream product

• 657408-07-6 dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane 
• 936951-72-3 (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(μ-Cl))2 
• 62-53-3 aniline 

Relevant articles and documents

Electronic effects on the selectivity of Pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: The competitive roles of amine binding and acidity

(Chemical Equation Presented) Electronic influence: Correlation between the relative binding constants of amines to isolated [SPhosPd(Ph)C;] (SPhos = 2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl) and the pKa of the amine complexes shows that the selectivity in the catalytic arylation of amines is influenced by the electronic properties of the amine. Selectivities observed in C-N cross-coupling reactions using neutral amines can be reversed using lithium amides.