956430-60-7Relevant academic research and scientific papers
Enantio- and diastereoselective synthesis of syn-β-hydroxyallylsilanes via a chiral (Z)-γ-silylallylboronate
Lira, Ricardo,Roush, William R.
, p. 4315 - 4318 (2008/03/11)
syn-β-Hydroxyallylsilanes of general structure 11 and 28 are prepared in 50-86% yield and 91-95% ee (for aliphatic aldehydes; 50% ee for benzaldehyde) via the BF3-Et2O-promoted γ-silylallylboration reactions, using reagents 14 and 15.
