31503-17-0

Upstream product

• 853911-96-3 (-)-(1R,2R,3R,4S)-1,7,7-trimethyl-2-phenyl-3-(triethylsilyloxy)-bicyclo[2.2.1]heptan-2-one 
• 77078-74-1 C₁₈H₂₄O₃ 
• 591-51-5 phenyllithium 
• 31503-04-5 Phenylborneol 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 7070-09-9 (1R,4R)-1,7,7-trimethyl-2-phenylbicyclo[2.2.1]hept-2-ene 
• 23963-14-6 (1S,4R)-4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,2'-[1,3]dioxolan]-3-one 
• 853911-91-8 (+)-1,1,7-trimethyl-2-(triethylsilyloxy)bicyclo[2.2.1]heptan-2-one 
• 853911-89-4 (+)-(1R,4S)-1,7,7-trimethyl-2-(triethylsilyloxy)bicyclo[2.2.1]hept-2-en 
• 959696-54-9 2-exo-Hydroxy-2-endo-phenylbornan-3-on 

Downstream Products

• 604774-85-8 (1R,2S,3R,4S)-2,3-O-(2-methylallylboryl)-2-phenyl-1,7,7-trimethylbornanediol 
• 604774-90-5 (1R,2S,3R,4S)-2,3-O-[(Z)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol 
• 604774-88-1 (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol 
• 77078-87-6 (1R,2S,3R,4S)-2,3-O-(allylboryl)-2-phenyl-1,7,7-trimethylbornanediol 
• 403806-10-0 (1R,2R,3R,4S)-3-methyl-2-(1,10,10-trimethyl-2-phenyl-3,5-dioxa-4-boratricyclo[5.2.1.0^0,0]dec-4-ylmethyl)but-2-enoic acid (1R,2S,3R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester 
• 956430-60-7 C₁₉H₂₇BO₃ 
• 959633-76-2 C₂₂H₂₉BO₄ 
• 1016982-80-1 C₂₂H₂₉BO₄ 
• 1314357-67-9 C₂₆H₂₉BF₂O₃ 
• 191658-67-0 2-((1R,2S,6R,7S)-1,10,10-Trimethyl-2-phenyl-3,5-dioxa-4-bora-tricyclo[5.2.1.0^2,6]dec-4-ylmethyl)-acrylic acid ethyl ester 

Relevant academic research and scientific papers

Practical and efficient multigram preparation of a camphor-derived diol for the enantioselective Lewis acid catalyzed allylboration of aldehydes

Chiral diols are important molecules with widespread use as chiral auxiliaries and ligands in enantioselective synthesis. Therefore, efficient and practical syntheses of highly dissymmetrical nonracemic diols are still a meaningful pursuit. Two new routes

Stereoselektive Synthese von Alkoholen, VI. Asymmetrische Synthesen von 4-Penten-2-ol ueber Allylboronsaeureester chiraler Glycole

Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1).The substituents affect the extent of asymmetric induction in an additive manner.Pentenol of 86percent enantiomeric purity was obtained using 2d as chiral matrix.