95645-73-1

Basic information

• Product Name: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-(m-chlorophenoxy)-17,18,19,20-tetranorprostenoate
• CAS NO: 95645-73-1
• Molecular Weight: 432.944
• Mol File: 95645-73-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-(m-chlorophenoxy)-17,18,19,20-tetranorprostenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-(m-chlorophenoxy)-17,18,19,20-tetranorprostenoate(95645-73-1)
• EPA Substance Registry System: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-(m-chlorophenoxy)-17,18,19,20-tetranorprostenoate(95645-73-1)

Safety Data

• Hazardous Substances Data: 95645-73-1(Hazardous Substances Data)

Upstream product

• 40665-94-9 dimethyl 3-(3-chlorophenoxy)-2-oxopropylphosphonate 
• 88736-15-6 2α-(7-methoxycarbonyl-4Z-heptenyl)-3β-formylcyclopentanone 

Downstream Products

• 131846-20-3 (Z)-8-{(1S,2S)-2-[(E)-(S)-4-(3-Chloro-phenoxy)-3-hydroxy-but-1-enyl]-5-oxo-cyclopentyl}-oct-4-enoic acid methyl ester 
• 131846-20-3 (Z)-8-{(1S,2S)-2-[(E)-(R)-4-(3-Chloro-phenoxy)-3-hydroxy-but-1-enyl]-5-oxo-cyclopentyl}-oct-4-enoic acid methyl ester 
• 131846-22-5 (Z)-8-{(1S,2S,5S)-2-[(E)-(S)-4-(3-Chloro-phenoxy)-3-hydroxy-but-1-enyl]-5-hydroxy-cyclopentyl}-oct-4-enoic acid methyl ester 

Relevant articles and documents

PROSTANOIDS XXXIII. INVESTIGATION OF THE POSSIBILITIES FOR CHEMOSELECTIVE AND STEREOSELECTIVE REDUCTION OF THE METHYL ESTERS OF (+/-)-1-HOMO-3,4-CIS-DIDEHYDRO-16-PHENOXY(m-CHLOROPHENOXY)-17,18,19,20-TETRANOR-9,15-DIKETO-13,14-TRANS-PROSTENOIC ACIDS

Chemoselective and stereoselective reduction of the methyl esters of 1-homo-3,4-cis-didehydro-16-phenoxy(m-chlorophenoxy)-17,18,19,20-tetranor-9,15-diketo-13,14-trans-prostenoic acid by triisobutylaluminum and L-selectride (methylene chloride, -70 deg C) gave the corresponding esters of 11-deoxyprostaglandins of the E and F types.