95661-79-3

Upstream product

• 14878-28-5 sodium tetracarbonyl cobaltate 
• 2751-90-8 tetraphenylphosphonium bromide 
• 15226-74-1 dicobalt octacarbonyl 
• 85236-24-4 [Fe2(CO)6(μ-CO)(μ-CHCH2)][P(C6H5)4] 

Downstream Products

• 137916-85-9 {Co₇N(CO)15}^(2-)*2P(C₆H₅)4⁽¹⁺⁾={Co₇N(CO)15}(P(C₆H₅)4)2 
• 103619-62-1 {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)} 
• 125899-99-2 (dihydridorhodium(triphenylphosphine)2(cHex-1,4-diazabutadiene))(cobalt(carbonyl)4) 

Relevant academic research and scientific papers

Charge-transfer salts of carbonylmetalates as outer-sphere ion pairs in photochemical and thermal electron transfer

Highly colored, crystalline salts result from the combination of the carbonylmetalates Co(CO)4-, Mn(CO)5- and HFe(CO)4- with perphenyl-phosphonium and sulfonium cations.The unique colors are associated with the interionic

Reactivity of a bridged vinyl dinuclear iron complex anion, [Fe2(CO)6(μ-CO)(μ-CHCH2)]-, toward dicobalt octacarbonyl: Synthesis of a mixed dinuclear iron cobalt bridged vinyl complex, FeCo(CO)7(μ-CHCH2), and its thermal conversion into a bridged vinylalkylidene mixed trinuclear cluster, FeCo2(CO) ...

Full title: Reactivity of a bridged vinyl dinuclear iron complex anion, [Fe2(CO)6(μ-CO)(μ-CHCH2)]-, toward dicobalt octacarbonyl: Synthesis of a mixed dinuclear iron cobalt bridged vinyl complex, FeCo(CO)7(μ-CHCH2), and its thermal conversion into a bridged vinylalkylidene mixed trinuclear cluster, FeCo2(CO)9(μ3-CCH2), and an ethylidyne mixed trinuclear cluster, Fe2Co(CO)10(μ3-CCH3). The reaction of [Fe2(CO)7(μ-CHCH2)][P-(C6H 5)4] with Co2(CO)8 at room temperature results in the formation of FeCo(CO)7(μ-CHCH2) (1) as well as the salt clusters [Fe(Co2(CO)9(μ3-CCH3)][P(C 6H5)4] (2) and [Co(C-O)4][P(C6H5)4]. Heating 1 in refluxing hexane results in redistribution to give the trinuclear clusters Co3(CO)9(μ3-CCH3), FeCo2(CO)9(μ3-CCH3) (3), and Fe2Co(CO)9(μ-CO)(μ3-CCH3) (4).