103619-62-1

Basic information

• Product Name: {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}
• Synonyms: {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}
• CAS NO: 103619-62-1
• Molecular Weight: 1003.63
• Mol File: 103619-62-1.mol

Chemical Properties

• CAS DataBase Reference: {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}(CAS DataBase Reference)
• NIST Chemistry Reference: {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}(103619-62-1)
• EPA Substance Registry System: {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}(103619-62-1)

Safety Data

• Hazardous Substances Data: 103619-62-1(Hazardous Substances Data)

Upstream product

• 52542-59-3 {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5} 
• 29477-07-4 {NEt₄}{Co(CO)4} 
• 86392-59-8 Mn(CO)5CCl₃ 
• 86392-60-1 Mn(CO)5CBr₃ 
• 14878-28-5 sodium tetracarbonyl cobaltate 
• 13859-41-1 sodium-manganese pentacarbonyl 
• 53433-12-8 [bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4] 
• 95661-79-3 (PPh₄)(Co(carbonyl)4) 

Downstream Products

• 103619-63-2 manganese(cobalt)2(carbonyl)10(μ3-methylidyne) 
• 96412-33-8 {bis(triphenylphosphine)nitrogen}{CF₃SO₃} 

Relevant articles and documents

Transition-metal trihalomethyl complexes as cluster-building reagents: Preparation and X-ray crystal structure of [PPN][MnCo2(CO)9(μ3-CCO)]

A new mixed-metal ketenylidene complex, [PPN][MnCo2(CO)9(μ3-CCO)] (1) (PPN+ = bis(triphenylphosphine)nitrogen(1+)), has been prepared from trihalomethyl manganese complexes, Mn(CO)5(CX3) (X = Cl or Br), in combination with [PPN][Co(CO)4]. Attempts to extend this technique to other trihalomethyl complexes and metal carbonyl anions did not yield any new cluster products. Instead, these reactions were characterized by electron-transfer chemistry, which resulted in oxidation of the anions. Crystal data for 1: triclinic space group P1; a = 14.859 (4) A?, b = 9.209 (1) A?, c = 16.701 (3) A?, a = 90.08 (2)°, β = 102.79 (2)°, γ = 89.99 (2)° Z = 2. Protonation of 1 leads to the new mixed-metal methylidyne MnCo2(CO)10(μ3-CH) (2).