95682-68-1Relevant academic research and scientific papers
Thermal Decomposition of t-Butyl Heptafluoroperoxybutyrate
Sawada, Hideo,Hagii, Hidehiko,Aoshima, Kazuyoshi,Arai, Takeshi
, p. 1161 - 1162 (1984)
The decomposition of t-butyl heptafluoroperoxybutyrate (TBH) was studied in both toluene and methanol.Kinetic and product studies from the thermolysis showed that this peroxy ester decomposes heterolytically in nonpolar solvents like toluene with homolysis, whereas in methanol this peroxy ester undergoes principally transesterification.
Perfluoropropylation of Furans, Thiophenes, and Pyridines with Bis(heptafluorobutyryl) Peroxide
Sawada, Hideo,Yoshida, Masato,Hagh, Hidehiko,Aoshima, Kazuyoshi,Kobayashi, Michio
, p. 215 - 220 (2007/10/02)
Bis(heptafluorobutyryl) peroxide (1) smoothly reacted with furans and thiophenes under mild conditions to regioselectively give 2-perfluoropropylfurans and thiophenes in high yields.Mechanistically, reactions with furans or thiophenes are considered to be initiated by one-electron transfers from substrates to 1.On the other hand, the perfluoropropylation of pyridine was proceeded by the usual free-radical substitution to a pyridinium salt by a heptafluoropropyl radical produced by the homolytic decomposition of 1.
