Bulletin of the Chemical Society of Japan p. 1161 - 1162 (1984)
Update date:2022-08-04
Topics:
Sawada, Hideo
Hagii, Hidehiko
Aoshima, Kazuyoshi
Arai, Takeshi
The decomposition of t-butyl heptafluoroperoxybutyrate (TBH) was studied in both toluene and methanol.Kinetic and product studies from the thermolysis showed that this peroxy ester decomposes heterolytically in nonpolar solvents like toluene with homolysis, whereas in methanol this peroxy ester undergoes principally transesterification.
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