95684-24-5Relevant articles and documents
First example of a Cu(i)-(η2-O,O)nitrite complex derived from Cu(ii)-nitrosyl
Kalita, Apurba,Kumar, Pankaj,Deka, Ramesh C.,Mondal, Biplab
, p. 1251 - 1253 (2012)
Copper(ii) complex, 1, of the bidentate ligand, L [L = bis(2-ethyl-4- methyl-imidazol-5yl)methane] has been synthesized and structurally characterized. Addition of nitric oxide gas to a degassed acetonitrile solution of 1 yielded the corresponding copper(ii)-nitrosyl complex, 2. In acetonitrile, complex 2 on reaction with water afforded the corresponding copper(i)-nitrite complex, 3. Single crystal structure of complex 3 reveals the bidentate nitrite (η2-O,O) bonding. This is the first example of a structurally characterized Cu(i)-(η2-O,O)nitrite complex with N-donor ligand. The sequence of the formation of these complexes is just the reverse of the key steps of the postulated nitrite reduction cycle by CuNiRs. The Royal Society of Chemistry 2012.
Reductive nitrosylation of nickel(II) complex by nitric oxide followed by nitrous oxide release
Ghosh, Somnath,Deka, Hemanta,Dangat, Yuvraj B.,Saha, Soumen,Gogoi, Kuldeep,Vanka, Kumar,Mondal, Biplab
, p. 10200 - 10208 (2016/07/06)
Ni(ii) complex of ligand L (L = bis(2-ethyl-4-methylimidazol-5-yl)methane) in methanol solution reacts with an equivalent amount of NO resulting in a corresponding Ni(i) complex. Adding further NO equivalent affords a Ni(i)-nitrosyl intermediate with the
