95712-46-2Relevant academic research and scientific papers
APPLICATION OF THE INTRAMOLECULAR DIELS-ALDER REACTIONS OF HETERODIENES TO THE SYNTHESES OF INDOLE ALKALOIDS
Martin, Stephen F.,Benage, Brigitte,Williamson, Sidney A.,Brown, Stephen P.
, p. 2903 - 2910 (2007/10/02)
A novel intramolecular Diels-Alder reaction involving the addition of an α,β-unsaturated aldehyde to an electron-deficient, dienophilic partner has been exploited as the key step in the development of a general entry to the heteroyohimboid and corynanthei
APPLICATIONS OF INTRAMOLECULAR DIELS-ALDER REACTIONS OF HETERODIENES. FACILE SYNTHESES OF HETEROYOHIMBINE ALKALOIDS TETRAHYDROALSTONINE AND AKUAMMIGINE
Martin, Stephen F.,Benage, Brigitte
, p. 4863 - 4866 (2007/10/02)
A facile, formal synthesis of the heteroyohimbine alkaloids tetrahydroalstonine (1) and akuammigine (2) has been completed in which the D/E ring system is constructed by the novel cyclization of the triene 10, a process which involves the intramolecular
