95728-87-3Relevant articles and documents
REFORMATSY TYPE REACTION BY MEANS OF Bu3SnAlEt2 or Bu3PbAlEt2
Tsuboniwa, Noriyuki,Matsubara, Seijiro,Morizawa, Yoshitomi,Oshima, Koichiro,Nozaki, Hitosi
, p. 2569 - 2572 (1984)
Treatment of α-halo carbonyl compounds with title Sn-Al or Pb-Al reagents provides enolates which react with aldehydes or ketones to give β-hydroxy carbonyl compounds effectively.
The chromium Reformatsky reaction: Access to adjacent quarternary centers
Wessjohann, Ludger,Wild, Harry
, p. 512 - 514 (2007/10/03)
α-Bromo ketones, -esters and -nitriles react with chromium dichloride and ketones in a Barbier-type reaction to yield the kinetic crossed aldol products with one or two new quarternary centers. The reaction does not require special activation of the reage