957799-23-4Relevant academic research and scientific papers
The aza-Morita-Baylis-Hillman reaction of N-thiophosphoryl imines catalyzed by 1,3,5-triaza-7-phosphaadamantane (PTA) - Convenient synthesis of α-methylene-β-amino ketone or acid derivatives
Xu, Xinyuan,Wang, Chungui,Zhou, Zhenghong,Tang, Xiaofang,He, Zhengjie,Tang, Chuchi
, p. 4487 - 4491 (2007)
In the presence of an effective air-stable nucleophilic trialkylphosphane orgaocatalyst, 1,3,5-triaza-7-phosphaadamantane, N-diethoxythiophosphorylimines 1 and N-diphenylthiophosphinoylimines 2 exhibited good reactivity in the methyl vinyl ketone or methy
1,3,5-triaza-7-phosphaadamantane (PTA): A practical and versatile nucleophilic phosphine organocatalyst
Tang, Xiaofang,Zhang, Bo,He, Zhengrong,Gao, Ruili,He, Zhengjie
, p. 2007 - 2017 (2008/09/18)
In this paper, the air-stable and readily available 1,3,5-triaza-7- phosphaadmantane (PTA) is reported as a practical and versatile nucleophilic phosphine organocatalyst. Under the mediation of 15-30 mol% of PTA, various electrophiles like aldehydes and i
