957997-69-2Relevant academic research and scientific papers
Synthesis of (arylalkenyl)silanes by palladium-catalyzed regiospecific and stereoselective allyl transfer from silyl-substituted homoallyl alcohols to aryl halides
Hayashi, Sayuri,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
, p. 12650 - 12651 (2007)
The reactions of silyl-substituted homoallyl alcohols with aryl halides under palladium catalysis result in regiospecific and stereoselective allyl transfer from the alcohols to aryl halides, offering modular synthesis of (E)-3-aryl-1-alkenyl-, (E)-1-aryl-2-alkenyl-, and optically active (E)-1-aryl-2-butenylsilanes. Copyright
