958264-85-2Relevant academic research and scientific papers
Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds
Bourque, Laura E.,Haile, Pamela A.,Loy, Janice M.N.,Woerpel
scheme or table, p. 5608 - 5613 (2009/12/01)
Allylic ethers undergo insertions of silylenes into C-O bonds to form allylic silanes. Silylene insertion into C-O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigma
Metal-catalyzed silylene insertions of allylic ethers: Stereoselective formation of chiral allylic silanes
Bourque, Laura E.,Cleary, Pamela A.,Woerpel
, p. 12602 - 12603 (2008/09/16)
Silylene insertion into allylic ethers occurs suprafacially to provide enantioenriched allylic silanes and disilanes. Silylene insertion to a variety of protected allylic alcohols utilizing silver- and copper-mediated conditions proved to be a general method for allylic silane formation. Allylic disilanes reacted similarly to allylic silanes, undergoing both annulation and allylation reactions. Copyright
