74262-58-1

Basic information

• Product Name: 4-benzyloxy-2-methylpent-2-ene
• Synonyms: 4-benzyloxy-2-methylpent-2-ene
• CAS NO: 74262-58-1
• Molecular Weight: 190.285
• Mol File: 74262-58-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-benzyloxy-2-methylpent-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-benzyloxy-2-methylpent-2-ene(74262-58-1)
• EPA Substance Registry System: 4-benzyloxy-2-methylpent-2-ene(74262-58-1)

Safety Data

• Hazardous Substances Data: 74262-58-1(Hazardous Substances Data)

Upstream product

• 4325-82-0 4-methyl pent-3-en-2-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 958264-83-0 C₂₁H₃₆OSi 
• 1180480-99-2 C₂₃H₄₄OSi₂ 
• 958264-85-2 C₂₃H₄₀OSi 
• 53346-05-7 2-(benzyloxy)propanal 
• 621-84-1 O-benzyl carbamate 
• 104882-75-9 benzyl 4-methylpent-3-en-2-ylcarbamate 
• 74263-03-9 2-Methyl-3-hydroxy-4-(benzyloxy)pentanoic acid 

Relevant articles and documents

Metal-catalyzed silylene insertions of allylic ethers: Stereoselective formation of chiral allylic silanes

Silylene insertion into allylic ethers occurs suprafacially to provide enantioenriched allylic silanes and disilanes. Silylene insertion to a variety of protected allylic alcohols utilizing silver- and copper-mediated conditions proved to be a general method for allylic silane formation. Allylic disilanes reacted similarly to allylic silanes, undergoing both annulation and allylation reactions. Copyright

Acyclic Stereoselection. 9. Stereochemistry of the Addition of Lithium Enolates to α-Alkoxy Aldehydes

The stereochemistry of addition of lithium enolates derived from esters and ketones to the α-alkoxy aldehydes 1-5 has been investigated.In all cases, the predominant product is that predicted by application of Felkin's model for asymmetric induction and by assuming the alkoxy group to be the "large" group.The Cram cyclic model for asymmetric induction is not followed.Stereostructures have been assigned by a combination of conversion to products of known stereostructure, 13C and 1H NMR correlations, and single-crystal X-ray analysis.