95843-67-7

Upstream product

• 62398-09-8 Acetic acid (2R,3S,6R)-2-acetoxymethyl-6-phenoxy-3,6-dihydro-2H-pyran-3-yl ester 
• 108-95-2 phenol 
• 2873-29-2 D-glucal triacetate 
• 113019-34-4 phenyl 4, 6-di-O-acetyl-2,3-dideoxy-1-O-α-D-erythro-hex-2-enopyranoside 

Downstream Products

• 113019-35-5 phenyl 4,6-di-O-benzyl-2,3-dideoxy-α,β-D-erythro-hex-2-enopyranoside 
• 119366-98-2 ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)-2-(ethoxycarbonyl)acetate 
• 119434-14-9 methyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)-2(R,S)-acetylacetate 
• 113084-95-0 ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)-2(R,S)-nitroacetate 
• 211674-14-5 4-((2R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-2H-pyran-2-yl)-1-(4-methoxy-phenyl)-3-methyl-5-phenyl-1H-pyrazole 
• 211674-12-3 4-((2R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-2H-pyran-2-yl)-3-methyl-5-phenyl-1-p-tolyl-1H-pyrazole 
• 211674-19-0 Acetic acid (2R,3S,6R)-2-acetoxymethyl-6-(3-methyl-5-phenyl-1-p-tolyl-1H-pyrazol-4-yl)-3,6-dihydro-2H-pyran-3-yl ester 
• 211674-08-7 4-((2R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-2H-pyran-2-yl)-1,3-dimethyl-5-phenyl-1H-pyrazole 
• 211674-04-3 2-((2R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-5,6-dihydro-2H-pyran-2-yl)-1-phenyl-butane-1,3-dione 
• 119367-00-9 3-(4',6'-di-O-benzyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)-3-acetylpropanone 
• 113019-36-6 phenyl 4,6-di-O-benzyl-2,3-dideoxy-α,β-D-erythro-hex-2-enopyranoside 
• 119366-97-1 ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-(ethoxycarbonyl)acetate 
• 119367-01-0 methyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2(R,S)-acetylacetate 

Relevant academic research and scientific papers

Synthesis of 4-(4,6-di-O-benzyl-2,3-dideoxy-β-D-erythro-hex-2- enopyranosyl)pyrazoles from 3,4,6-tri-O-acetyl-D-glucal

3-(4,6-Di-O-benzyl-2,3-dideoxy-b-D-erythro-hex-2-enopyranosyl)-2,4- pentanedione and its analogue 2-(4,6-di-O-benzyl-2,3-dideoxy-β-D-erythro- hex-2-enopyranosyl)-1-phenyl-1,3-butanedione, prepared from 3,4,6-tri-O- acetyl-1,5-anhydro-2-deoxy-D-arabino-hex

Palladium(0)-Based Approach to Functionalized C-Glycopyranosides

Phenyl 4,6-di-O-benzyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside 4α or 5β reacts with ethyl malonate, acetylacetone, methyl acetylacetate, ethyl nitroacetate, and ethyl nitromalonate under neutral conditions in the presence of Pd(0) to give regiospecifica