95844-02-3

Upstream product

• 280-57-9 1,4-diaza-bicyclo[2.2.2]octane 
• 100-39-0 benzyl bromide 

Downstream Products

• 1689-71-0 cis-1,2-diphenyloxirane 
• 1439-07-2 trans-Stilbene oxide 
• 280-57-9 1,4-diaza-bicyclo[2.2.2]octane 
• 57455-05-7 benzyl trideuteromethyl ether 

Relevant academic research and scientific papers

A highly luminescent and stable copper halide ionic hybrid structure with an anionic CuBr2(tpp)2module

Here, we report a novel copper bromide ionic compound (bz-ted)CuBr2(tpp)2·H2O (1, tpp = triphenylphosphine, and bz-ted = 1-benzyl-1,4-diazabicyclo[2.2.2]octan-1-ium) by a facile wet chemistry method. The inorganic module o

Directing Aluminum Atoms into Energetically Favorable Tetrahedral Sites in a Zeolite Framework by Using Organic Structure-Directing Agents

The Al location in zeolites can have massive influences on the zeolite properties because it directly correlates with the cationic active sites. Herein, the synthesis of IFR zeolites with controlled Al distribution at different tetrahedral sites (T sites)

All-in-One: Achieving Robust, Strongly Luminescent and Highly Dispersible Hybrid Materials by Combining Ionic and Coordinate Bonds in Molecular Crystals

Extensive research has been pursued to develop low-cost and high-performance functional inorganic-organic hybrid materials for clean/renewable energy related applications. While great progress has been made in the recent years, some key challenges remain

Benzylic Ammonium Ylide Mediated Epoxidations

A high yielding synthesis of stilbene oxides using ammonium ylides has been developed. It turned out that the amine leaving group plays a crucial role as trimethylamine gives higher yields than DABCO or quinuclidine. The amine group also influences the diastereoselectivity, and detailed DFT calculations to understand the key parameters of these reactions have been carried out.

A simple, efficient and green procedure for Knoevenagel condensation catalyzed by [C4dabco][BF4] ionic liquid in water

A convenient and rapid method for Knoevenagel condensation has been developed by using DABCO-base ionic liquid catalysts. This method is applicable to a wide range of aromatic/aliphatic/heterocyclic/α,β-unsaturated aldehydes and ketones with active methyl

Organocatalytic activation of TMSCN by basic ammonium salts for efficient cyanation of aldehydes and imines

Basic ammonium salts act as highly effective catalysts for the cyanosilylation of aldehydes and in Strecker-type aminonitrile synthesis using TMSCN as cyanide source at 25 °C under extremely mild conditions, affording very good to excellent yields of silylated cyanohydrins and α-aminonitriles.

Polycations-12. The synthesis of liquid ionic phosphates (lips) from mono- and polycationic ammonium halides

Preparations are reported for an extensive series of phosphate salts of polyammonium species from the corresponding halide salts. The phosphate salts, as anhydrous materials, are liquid at or near room temperature. Three approaches for the preparation of these materials are noted, including treatment with aqueous hexafluorophosphoric acid, classical ion exchange methods, and treatment with 85% phosphoric acid. The last of these provides the most desirable results. Several monocationic phosphate salts have also been prepared for comparison with other types of ionic liquids.

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate (BAABCPS) 1, readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium peroxodisulfate converts thiols, sulfoxides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds respectively.

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4- diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and α-sulfinyl oximes to the corresponding carbonyl compounds and β-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.

An easy and efficient method for oxidation of alcohols and aromatic amines to the corresponding carbonyl and azo compounds under non-aqueous and neutral conditions

1-Benzyl-1-aza-4-azoniabicyclooctane periodate 1, readily prepared as an orange solid from commercially available 1,4-diazobicyclooctane, is useful for oxidation in anhydrous conditions.The reagent converts alcohols to die corresponding carbonyl compounds, α hydroxy ketones to diketones, and aromatic amines to azo compounds, in me excellent yields.The reagent ineffective in oxidising double bonds, aldehydes and ketones.