958658-48-5

Basic information

• Product Name: 2-methyl-2-(3-nitro-4-phenylbutyl)-1,3-dioxolane
• Synonyms: 2-methyl-2-(3-nitro-4-phenylbutyl)-1,3-dioxolane
• CAS NO: 958658-48-5
• Molecular Weight: 265.309
• Mol File: 958658-48-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-methyl-2-(3-nitro-4-phenylbutyl)-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-2-(3-nitro-4-phenylbutyl)-1,3-dioxolane(958658-48-5)
• EPA Substance Registry System: 2-methyl-2-(3-nitro-4-phenylbutyl)-1,3-dioxolane(958658-48-5)

Safety Data

• Hazardous Substances Data: 958658-48-5(Hazardous Substances Data)

Upstream product

• 109-49-9 5-Hexen-2-one 
• 113810-79-0 5-nitrohex-5-en-2-one 
• 1383810-10-3 5-nitro-6-phenylhexan-2-one 
• 107-21-1 ethylene glycol 
• 6125-24-2 2-Phenylnitroethane 

Downstream Products

• 89588-35-2 4-(2-Methyl-[1,3]dioxolan-2-yl)-1-phenyl-butan-2-one 
• 50397-92-7 3-methyl-2-phenylcyclopent-2-en-1-one 
• 32776-14-0 1-phenyl-hexane-2,5-dione 

Relevant articles and documents

Sequential Reduction of Nitroalkanes Mediated by CS2 and Amidine/Guanidine Bases: A Controllable Nef Reaction

In this letter, we describe a mild, functional group-tolerant reductive Nef reaction that utilizes CS2 and an amidine or guanidine base to sequentially cleave N-O bonds. These conditions transform secondary nitroalkanes to ketones via an isolable oxime with minimal erosion at labile stereogenic carbons, show excellent compatibility with groups sensitive to oxidizing or reducing conditions, display good scalability, and are well-suited for generating useful 3-pyrrolidinone motifs from readily accessible 1,3-dipolar cycloaddition products.