958666-90-5Relevant academic research and scientific papers
Dynamic kinetic resolution of primary alcohols with an unfunctionalized stereogenic center in the β-position
Struebing, Dirk,Krumlinde, Patrik,Piera, Julio,Baeckvall, Jan-E.
, p. 1577 - 1581 (2007)
Primary alcohols with an unfunctionalized stereogenic center in the β-position undergo an enzyme- and metal-catalyzed dynamic kinetic resolution (DKR). The in situ racemization of the primary alcohol, required for the DKR, takes place via: (i) ruthenium-c
Isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters
Smith, Andrew D.,Wu, Jiufeng,Young, Claire M.
supporting information, (2020/12/21)
A protocol for the isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters using Hantzsch ester has been developed. Good to excellent yields are observed using α,β-unsaturated aryl esters bearing electron-withdrawing β-subs
