95898-05-8

Basic information

• Product Name: 2,3,4-tri-O-benzyl-α-D-xylopyranosyl fluoride
• Synonyms: 2,3,4-tri-O-benzyl-α-D-xylopyranosyl fluoride
• CAS NO: 95898-05-8
• Molecular Weight: 422.496
• Mol File: 95898-05-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3,4-tri-O-benzyl-α-D-xylopyranosyl fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4-tri-O-benzyl-α-D-xylopyranosyl fluoride(95898-05-8)
• EPA Substance Registry System: 2,3,4-tri-O-benzyl-α-D-xylopyranosyl fluoride(95898-05-8)

Safety Data

• Hazardous Substances Data: 95898-05-8(Hazardous Substances Data)

Upstream product

• 95898-04-7 1-O-acetyl 2,3,4-tri-O-benzyl-α,β-D-xylopyranose 
• 18039-26-4 2,3,4-tri-O-benzyl-D-xylopyranose 
• 521304-45-0 phenyl 2,3,4-tri-O-acetyl-1-thio-1-deoxy-D-xylopyranoside 
• 62446-93-9 1,2,3,4-tetra-O-acetyl-D-xylopyranose 
• 87-72-9 D-Xylose 
• 100-39-0 benzyl bromide 

Downstream Products

• 86450-75-1 baiyunoside 
• 86450-75-1 (2S,3R,4S,5R)-2-{(2S,3R,4S,5S,6R)-2-[(2R,4aR,8aS)-5-(2-Furan-3-yl-ethyl)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy]-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yloxy}-tetrahydro-pyran-3,4,5-triol 
• 86450-75-1 (2R,3R,4S,5R)-2-{(2R,3R,4S,5S,6R)-2-[(2R,4aR,8aS)-5-(2-Furan-3-yl-ethyl)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy]-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yloxy}-tetrahydro-pyran-3,4,5-triol 
• 86450-75-1 (2S,3R,4S,5R)-2-{(2S,3R,4S,5S,6R)-2-[(2S,4aS,8aR)-5-(2-Furan-3-yl-ethyl)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy]-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yloxy}-tetrahydro-pyran-3,4,5-triol 
• 115243-91-9 C₅₈H₇₂O₁₄ 
• 140420-47-9 allyl O-(2,3,4-tri-O-benzyl-β-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-α-D-glucopyranoside 
• 140420-44-6 allyl O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-α-D-glucopyranoside 
• 140420-59-3 allyl O-(2,3,4-tri-O-benzyl-β-D-xylopyranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside 
• 140420-57-1 allyl O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside 
• 140420-60-6 1-propenyl O-(2,3,4-tri-O-benzyl-β-D-xylopyranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside 
• 140420-58-2 1-propenyl O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside 
• 115243-91-9 C₅₈H₇₂O₁₄ 
• 115243-91-9 C₅₈H₇₂O₁₄ 
• 115243-86-2 Acetic acid (2R,3R,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-[(2R,4aR,8aS)-5-(2-furan-3-yl-ethyl)-1,1,4a,6-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-yloxy]-5-hydroxy-tetrahydro-pyran-4-yl ester 

Relevant articles and documents

Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.