959080-54-7Relevant academic research and scientific papers
Reaction Products and Process of 2-Chloroethyl Ethyl Sulfide in Microemulsion Media
Mei-Ling, Lei,Hai-Ling, Xi,Ming, Shen,Ling, Yuan,Shi-Tong, Han
, p. 387 - 393 (2014)
The reaction of 2-chloroethyl ethyl sulfide was investigated in several oil-in-water microemulsions. The reaction products were identified by GC/MS, NMR, and LC/MS, and the reaction process was monitored by measuring peak height of reaction products and 2-chloroethyl ethyl sulfide with time by 1H NMR spectroscopy. The result showed that 2-chloroethyl ethyl sulfide degraded to 2-hydroxyethyl ethyl sulfide, cyclic sulfonium ion, open chain sulfonium chloro ion and sulfonium hydroxyl ion, and the reaction proceeded via a cyclic sulfonium ion intermediate. Based on the NMR results, a pseudoternary model was established for the reaction process of 2-chloroethyl ethyl sulfide in microemulsion.
