959129-16-9Relevant academic research and scientific papers
Enantioselective catalysis of ketoester-ene reaction of silyl enol ether to construct quaternary carbons by chiral dicationic palladium(II) complexes
Mikami, Koichi,Kawakami, Yuji,Akiyama, Katsuhiro,Aikawa, Kohsuke
, p. 12950 - 12951 (2008/09/17)
Dicationic SEGPHOS-Pd complex-catalyzed ketoester-ene reaction with silyl enol ether can be achieved to produce an ene product with a quaternary carbon center in high yield and enantioselectivity. Even lower catalyst loading (up to 0.01 mol%) can be perfo
