152718-39-3

Upstream product

• 167865-63-6 1-tert-butyl(diphenyl)silyl-1-methylepoxyethane 
• 67-64-1 acetone 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 959129-16-9 C₂₄H₃₂O₄Si 

Relevant academic research and scientific papers

Gold-acetonyl complexes: From side-products to valuable synthons

A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH3)]. The approach capitalizes on the formation of a decomposition product observed in the course of the synthesis of [Au(IPr)(Cl)]. A library of gold acetonyl complexes containing the most common N-heterocyclic carbene (NHC) ligands has been synthesized. These acetonyl complexes are good synthons for the preparation of numerous organogold complexes. Moreover, they have proven to be precatalysts in common gold(I)-catalyzed reactions. Organogold: A library of [Au(NHC)(acetonyl)] complexes (NHC=N-heterocyclic carbene) has been easily synthesized. These complexes represent valuable synthetic precursors to a plethora of organogold species, as well as active catalysts for gold(I)-catalyzed reactions (see scheme).

Enantioselective catalysis of ketoester-ene reaction of silyl enol ether to construct quaternary carbons by chiral dicationic palladium(II) complexes

Dicationic SEGPHOS-Pd complex-catalyzed ketoester-ene reaction with silyl enol ether can be achieved to produce an ene product with a quaternary carbon center in high yield and enantioselectivity. Even lower catalyst loading (up to 0.01 mol%) can be perfo

Regio- and stereospecific cleavage of silyl- and disilylepoxides with lithium diphenylphosphide

Unsubstituted or α- and β-C-substituted silylepoxides react stereospecifically with lithium diphenylphosphide, optionally followed by methylation, to give vinylphosphonium iodides or vinylphosphine oxides resulting from α-opening and silyl enol ethers, vi