95920-08-4Relevant academic research and scientific papers
Organophosphorus Compounds, 111. Phosphinic and Thiophosphinic Cyanides as Fluorescent SH-selective Reagents
Horner, Leopold,Lindel, Hans
, p. 676 - 682 (2007/10/02)
The fluorescent thiophosphinic cyanides 7 and 8 are SH-selective, the corresponding thiophosphinic chlorides 5 and 6 are in general NH2-selective (exception: the methyl ester of cysteine is S-thiophosphinoylated).The fluorescent dithiophosphinic esters, for example 11 - 14, obtained in this way, are of analytical value.The SH-compounds are regenerated by fluorolysis of the dithiophosphinic esters.Diphenylthiophosphinic cyanide is more suitable for the application in synthesis than the compounds 7 and 8.
