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1638-86-4

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1638-86-4 Usage

Chemical Properties

clear colourless liquid

Uses

Diethyl phenylphosphonite is an aromatic compound with catalytic and antibacterial applications.

Check Digit Verification of cas no

The CAS Registry Mumber 1638-86-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,6,3 and 8 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1638-86:
(6*1)+(5*6)+(4*3)+(3*8)+(2*8)+(1*6)=94
94 % 10 = 4
So 1638-86-4 is a valid CAS Registry Number.
InChI:InChI=1/C10H15O2P/c1-3-11-13(12-4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3

1638-86-4 Well-known Company Product Price

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  • Alfa Aesar

  • (B24836)  Diethyl phenylphosphonite, 98%   

  • 1638-86-4

  • 5g

  • 1001.0CNY

  • Detail
  • Alfa Aesar

  • (B24836)  Diethyl phenylphosphonite, 98%   

  • 1638-86-4

  • 25g

  • 2604.0CNY

  • Detail
  • Alfa Aesar

  • (B24836)  Diethyl phenylphosphonite, 98%   

  • 1638-86-4

  • 100g

  • 7656.0CNY

  • Detail

1638-86-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name DIETHYL PHENYLPHOSPHONITE

1.2 Other means of identification

Product number -
Other names Diethyl phenylphosphonite

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1638-86-4 SDS

1638-86-4Relevant articles and documents

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Rhomberg,A.,Tavs,P.

, p. 105 - 108 (1967)

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Co-ordination Kinetics of Some Aliphatic Amines towards the Photogenerated Transient 'CoH3'

Onishi, Masayoshi,Takaki, Isato,Hiraki, Katsuma,Oishi, Shigero

, p. 2675 - 2676 (1988)

Time-resolved adsorption spectra were observed after nitrogen-laser flash photolysis of toluene solutions of in the presence of some aliphatic amines, and second-order rate constants were evaluated for co-ordination of the amines to the co-ordinatively unsaturated transient 'CoHL3' photogenerated.The steric bulk of substituents on the amine nitrogens is a dominant factor in the magnitude of the constants.The CoHL3(amine) adducts were also formed upon continuoes photolysis with a high-pressure mercury lamp, and found to be stable at temperatures lower than -40 deg C, on the basis of their (31)P n.m.r. and visible absorption spectra.

Silver-Catalyzed Regioselective Phosphorylation of para-Quinone Methides with P(III)-Nucleophiles

Liu, Yu,Tang, Ke-Wen,Wong, Wai-Yeung,Xie, Jun,Xiong, Biquan,Xu, Shipan,Xu, Weifeng

, p. 14983 - 15003 (2021/11/12)

A simple and efficient method for the silver-catalyzed regioselective phosphorylation of para-quinone methides (p-QMs) with P(III)-nucleophiles (P(OR)3, ArP(OR)2, Ar2P-OR) has been established via Michaelis-Arbuzov-type reaction. A broad range of P(III)-nucleophiles and para-quinone methides are well tolerated under the mild conditions, giving the expected diarylmethyl-substituted organophosphorus compounds with good to excellent yields. Moreover, a series of corresponding enantiomers can be obtained by employing dialkyl arylphosphonite (ArP(OR)2) as substrates. The control experiments and 31P NMR tracking experiments were also performed to gain insights for the plausible reaction mechanism. This protocol may have significant implications for the formation of C(sp3)-P bonds in Michaelis-Arbuzov-type reactions.

New preparation method of first-class phenyl phosphine oxide initiator

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Paragraph 0049-0051, (2020/03/05)

The invention provides a new preparation method of a first-class phenyl phosphine oxide initiator. The method comprises the steps that (1) benzene and aluminum trichloride are added into a reaction vessel and stirred uniformly, then phosphorus trichloride is added, the temperature is slowly increased, and after a complete reaction, the temperature is reduced to room temperature; (2) a reaction mixture obtained in the step (1) is slowly added dropwise into a solvent containing a decomplexing agent, and the temperature is controlled for decomplexing; (3) a decomplexing product obtained in the step (2) is filtered to separate solids, and filtrate is subjected to pressure reduction distillation to obtain phenyl dialkoxy phosphine or diphenyl alkoxy phosphine; (4) a product obtained in the step(3) is dissolved in a benzene or methylbenzene solvent, and a trichloromethyl acetyl compound is added dropwise for a reaction; and (5) a solution obtained after the complete reaction in the step (4)is subjected to low-pressure desolvation, and light-yellow liquid or solid, namely the phenyl phosphine oxide initiator, is obtained through crystallization, suction filtering and drying. The methodhas the advantages that raw materials are easy to obtain, cost is low, operation is easy to perform, and mass production can be realized.

Preparation of O-Protected Cyanohydrins by Aerobic Oxidation of α-Substituted Malononitriles in the Presence of Diarylphosphine Oxides

Zhang, Dapeng,Lian, Mingming,Liu, Jia,Tang, Shukun,Liu, Guangzhi,Ma, Cunfei,Meng, Qingwei,Peng, Haisheng,Zhu, Daling

supporting information, p. 2597 - 2601 (2019/04/17)

A mild, reagent-cyanide-free, and efficient synthesis of O-phosphinoyl-protected cyanohydrins from readily available α-substituted malononitriles was realized using diarylphosphine oxides in the presence of O2. Mechanistic studies indicated that in addition to the initial aerobic oxidation of the malononitrile derivative notable features of this process include the formation of a tetrahedral intermediate and a subsequent intramolecular rearrangement. The phosphinoyl-protecting group can be removed by alcoholysis or by reduction with DIBAL-H.

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