95950-75-7Relevant academic research and scientific papers
Metal-free cycloisomerizations of: O -alkynylbiaryls
Zhang, Jingyi,Li, Siqi,Qiao, Yan,Peng, Cheng,Wang, Xiao-Na,Chang, Junbiao
supporting information, p. 12455 - 12458 (2018/11/20)
We describe a novel and highly efficient metal-free strategy to construct 9,9-disubstituted fluorenes and phenanthrenes via the TfOH-catalyzed cycloisomerizations of o-alkynylbiaryls. Notably, the significant effects of the electronic properties and steric hindrance of the alkyne terminus on the reaction selectivity have been observed.
N-heterocyclic-carbene complexes readily prepared from Di-μ-hydroxopalladacycles catalyze the Suzuki arylation of 9-bromophenanthrene
Serrano, J. Luis,Perez, Jose,Garcia, Luis,Sanchez, Gregorio,Garcia, Joaquin,Lozano, Pedro,Zende, Vidya,Kapdi, Anant
, p. 522 - 533 (2015/02/05)
New cyclometalated palladium complexes of general formula [Pd(Bmim)(X)(C^N)] have been synthesized by a novel reaction route involving di-μ-hydroxo-palladacycles [{Pd(μ-OH)(C^N)}2] (C^N = 2-benzoylpyridine (Bzpy
