95980-86-2

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 75-64-9 tert-butylamine 

Downstream Products

• 116762-41-5 racemic N-t-butyl-P-phenylphosphonamidothioic acid 
• 116762-40-4 (S)-α-methylbenzylamine salt of N-t-butyl-P-phenylphosphonamidothioic acid 
• 116762-45-9 racemic N-t-butyl-N'-t-pentyl-P-phenylphosphonic diamide 
• 855525-63-2 S-methyl N-tert-butyl-P-phenylphosphonamidothioate 1-SMe 
• 111783-64-3 racemic N-t-butyl-P-phenylphosphonamidic chloride 
• 84718-91-2 methyl N-t-butyl-P-phenylphosphonamidate 
• 15916-99-1 N,N'-Di-tert-butyl-P-phenylphosphonyldiamid 
• 116762-44-8 racemic N-t-butyl-P-phenylphosphonamidothioic chloride 

Relevant academic research and scientific papers

Associative and Dissociative Mechanisms for the Rections of N-t-Butyl-P-phenylphosphonamidic Chloride with Isopropylamine and t-Butylamine: Competitive, Kinetic, and Stereochemical Studies

The substitution reactions of N-t-butyl-P-phenylphosphonamidic chloride (4a) with isopropylamine and t-butylamine (or t-pentylamine in stereochemical experiments) in MeCN at 0 deg C can apparently proceed by one associative and two dissociative mechanisms

Synthesis of New Cyclopentadienyl-, Indenyl- and Fluorenylphosphanes by the Reaction of Carbanions of the Cyclopentadienyl Type with Alkyl(aryl)chloro-N,N-dialkylaminophosphanes

A number of alkyl(aryl)chloro-N,N-dialkylaminophosphanes RP(Cl)NR1R2 (1a-o) were synthesized starting from alkyl(aryl)dichlorophosphanes RPCl2 and amines by a convenient procedure with nearly quantitative yields. The reactivity of alkyl(aryl)-N,N-dialkylamino(halogeno)phosphanes RP(Hal)NR1R2 (Hal = Cl, I) with cyclopentadienyl, bis(cyclopentadienyl), indenyl, bis(indenyl) and fluorenyl carbanions has been investigated. The new aminocyclopentadienylphosphanes RnCp(R)PNR1R2 2a-f and 3a-c (RnCp = Ind, Flu, Cp2CMe2, Ind2CEt2, Ind2(CH2)2) were characterized by spectroscopic techniques and elemental analyses. Flu(t-Bu)PN(H)t-Bu (2f) was characterized by X-ray diffraction analysis.