95999-38-5

Basic information

• Product Name: Cyclohexanecarbonyl bromide, 1-bromo-
• Synonyms: 1-bromocyclohexanecarbonyl bromide;t-bromocyclohexanecarbonyl bromide;1-Brom-cyclohexancarbonylbromid;Cyclohexanecarbonyl bromide,1-bromo;1-Brom-hexahydrobenzoylbromid
• CAS NO: 95999-38-5
• Molecular Formula: C7H10Br2O
• Molecular Weight: 269.964
• Mol File: 95999-38-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 113-115 °C(Press: 13 Torr)
• Density: 1.834±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Cyclohexanecarbonyl bromide, 1-bromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarbonyl bromide, 1-bromo-(95999-38-5)
• EPA Substance Registry System: Cyclohexanecarbonyl bromide, 1-bromo-(95999-38-5)

Safety Data

• Hazardous Substances Data: 95999-38-5(Hazardous Substances Data)

Upstream product

• 98-89-5 Cyclohexanecarboxylic acid 
• 10500-30-8 cyclohexanoyl bromide 

Downstream Products

• 651325-99-4 1-(1-bromo-cyclohexyl)-2-diazo-ethanone 
• 7476-59-7 1-bromo-cyclohexanecarboxylic acid amide 
• 22589-13-5 pentamethyleneketene 
• 1617-22-7 cyclohex-1-enecarboxylic acid ethyl ester 
• 56077-29-3 2-bromo-1-(1-bromocyclohexyl)ethanone 
• 95999-30-7 [cyclohexylidene(phenyl)methoxy]trimethylsilane 
• 95999-29-4 (1-Cyclohexylidene-pentyloxy)-trimethyl-silane 
• 95999-27-2 1-(1-Methyl-cyclohexyl)-pentan-1-one 
• 64639-28-7 (1-trimethylsiloxyethylidene)cyclohexane 
• 950-21-0 dispiro[5.1.5.1]tetradecane-7,14-dione 
• 820963-56-2 acetic acid 3-(tert-butyl-dimethyl-silanyloxy)-3-cyclohexylidene-1-(1-phenethyl-but-3-enyloxy)-propyl ester 
• 820963-46-0 3-(tert-butyl-dimethyl-silanyloxy)-3-cyclohexylidene-propionic acid 1-phenethyl-but-3-enyl ester 

Relevant articles and documents

The synthetic protocol for α-bromocarbonyl compounds via brominations

α-Bromocarbonyl compound easily generates α-radicals in the presence of a proper initiator, such as copper salt. Recently, tertiary-alkylation reaction using α-bromocarbonyl compound as a tertiary alkyl source is recognized as one of the most important alkylation reactions. The reactions using α-bromocarbonyl compound are increasing, whereas synthetic methods for various functionalized α-bromocarbonyl compounds are not summarized. Generally, α-bromocarbonyl compounds can be synthesized from the corresponding carboxylic acids via α-bromo acid bromide, but the brominations of carboxylic acids are sometimes problematic. In this paper, we will report some technical information for a bromination and synthetic examples of representative α-bromocarbonyl compounds.