960078-99-3

Upstream product

• 960078-99-3 Fe₂(1,3-propanedithiolate)(CO)₄(dppe) 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 201230-82-2 carbon monoxide 

Downstream Products

• 936911-90-9 [Fe2(CO)4(μ-pdt)(μ-dppm)] 
• 1350823-71-0 [Fe2(CO)3(trimethyl phosphite)(κ2-dppe)(μ-pdt)] 
• 1350823-73-2 [Fe2(CO)2(trimethyl phosphite)2(κ2-dppe)(μ-pdt)] 

Relevant academic research and scientific papers

Controllable electrochemical synthesis of Mono- and Di-substituted diphosphine complexes related to [Fe-Fe]-hydrogenase

By the electrocatalytic reactions of [Fe2(CO) 6(μ-pdt)] (1) (pdt = SCH2CH2CH2S) with bidentate phosphine complexes dppx (dppm = PPh2CH 2PPh2, dppe = PPh2(CH

Oxidatively induced reactivity of [Fe2(CO)4(κ 2-dppe)(μ-pdt)]: An electrochemical and theoretical study of the structure change and ligand binding processes

The one-electron oxidation of the diiron complex [Fe2(CO) 4(κ2-dppe)(μ-pdt)] (1) (dppe = Ph 2PCH2CH2PPh2; pdt = S(CH 2)3S) has been investigated in the abse

Electron-transfer-catalyzed rearrangement of unsymmetrically substituted diiron dithiolate complexes related to the active site of the [FeFe]-hydrogenases

Novel asymmetrically substituted azadithiolate compounds [Fe 2(CO)4(κ2-dppe){μ-SCH 2N(R)CH2S}] (R = iPr, 1a; CH2CH 2OCH3, 1b; CH2C6H5, 1c) have been synthesized by treatment of [Fe2(CO)6(μ-adt)] [adt = SCH2N(R)CH2S, with R = iPr, CH 2CH2OCH3, CH2C6H 5] with dppe (dppe = Ph2PCH2CH 2PPh2) in refluxing toluene in the presence of Me 3NO. 1a-c have been characterized by single-crystal X-ray diffraction analyses. The electrochemical investigation of 1a-c and of [Fe 2(CO)4(κ2-dppe)(μ-pdt)] (1d) [pdt = S(CH2)3S] in MeCN- and THF-[NBu4][PF 6] has demonstrated that the electrochemical reduction of 1a-d gives rise to an Electron-transfer-catalyzed (ETC) isomerization to the symmetrical isomers 2a-d where the dppe ligand bridges the iron centers. Compounds 2a-d were characterized by IR and NMR spectroscopy, elemental analysis, and X-ray crystallography for 2a.