960127-75-7Relevant academic research and scientific papers
Polyoxometalates: Powerful catalysts for atom-efficient cyclopropanations
Boldini, Irene,Guillemot, Geoffroy,Caselli, Alessandro,Proust, Anna,Gallo, Emma
, p. 2365 - 2370 (2010)
The polyoxometalate-based catalytic cyclopropanation of olefins by ethyl diazoacetate (EDA) is reported. The outstanding catalyst productivity (TONs up to 100,000) and the use of equimolar EDA/olefin ratio confer to the methodology a high sustainability. Preliminary mechanistic investigations are also discussed.
