96014-15-2Relevant academic research and scientific papers
Rearrangements of trihalomethyl ketones
Braverman, Samuel,Cherkinsky, Marina,Kumar, E. V. K. Suresh,Gottlieb, Hugo E.
, p. 4521 - 4529 (2000)
Trihalomethyl ketones have been prepared and their reactivity under basic conditions was investigated in terms of competition between 1,2- vs. 1,3-elimination and nucleophilic substitution. Favorskii rearrangement was the preferred process, but in those c
A CONVENIENT METHOD FOR THE SYNTHESIS OF αβ-UNSATURATED CARBOXYLIC ACID AMIDES UTILIZING A NEW HETERO-BIFUNCTIONAL REAGENT, DMPATT
Nagao, Yoshimitsu,Hagiwara, Yuichi,Yamada, Shozo,Ochiai, Masahito,Fujita, Eiichi
, p. 4686 - 4689 (2007/10/02)
As a new extention of monitored aminolysis of 3-acyl-1,3-thiazolidine-2-thione(ATT), a convenient procedure for the synthesis of αβ-unsaturated carboxylic acid amides has been developed using a new hetero-bifunctional reagent, 3-dimethylphosphonoacetyl-1,3-thiazolidine-2-thione (DMPATT).DMPATT was effectively used as the bridging reagent between amino (or imino) compounds and aldehydes (or ketone) to afford various olefinic amides in good yields.KEYWORDS - thiazolidine-2-thione; hetero-bifunctional reagent; αβ-unsaturated amide; Wittig reaction; ferulyltryptamine
