96029-10-6Relevant academic research and scientific papers
The Reactions of arachno-Decaboranyl Complexes L2B10H12(L= Two-electron Donor Ligand) with some Platinum(II) Compounds; Nuclear Magnetic Resonance Studies and the Crystal and Molecular Structure of
Crook, Janet E.,Greenwood, Norman N.,Kennedy, John D.,McDonald, Walter S.
, p. 2487 - 2496 (2007/10/02)
The reactions of arachno-6,9-(SMe2)2B10H12 and of arachno-6,9-(MeCN)2B10H12 with the complex cis- give moderate yields of the nido-platinaundecaborane which has been characterised by single-crystal X-ray diffraction analysis.Analogous reactions with the dimeric species 2> (R3 = Me3-nPhn'n = 0,1 or 2), by contrast, give the nido-platinaundecaboranes which have been characterized by single-and multiple-resonance n.m.r. spectroscopy.Additional products of the reactions include the arachno nine-vertex species 4-(MeCN)B9H13 and 4-(SMe2)B9H13.
