960294-92-2Relevant academic research and scientific papers
Transmetallation between Metal-Only Lewis Pairs: A new rhodium alane complex
Bauer, Juergen,Braunschweig, Holger,Radacki, Krzysztof
, p. 10407 - 10409,3 (2012)
In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me3P)2Rh→AlCl3], is reported. Given that direct synthesis using aluminium trichloride failed, a convenient transmetallation reaction was applied. The new MOLP was analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.
Interaction between d- and p-block metals: Synthesis and structure of platinum-alane adducts
Braunschweig, Holger,Gruss, Katrin,Radacki, Krzysztof
, p. 7782 - 7784 (2008/09/18)
(Figure Presented) You'll never walk alane: An intriguing T-shaped platinum-alane adduct results from the almost quantitive reaction of [Pt(PCy3)2] with AlX3 (X = Cl, Br, I). The compound [(Cy3P)2Pt-A
