960378-34-1

Basic information

• Product Name: [Lu(phenyl)3(THF)2]
• CAS NO: 960378-34-1
• Molecular Weight: 550.498
• Mol File: 960378-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Lu(phenyl)3(THF)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Lu(phenyl)3(THF)2](960378-34-1)
• EPA Substance Registry System: [Lu(phenyl)3(THF)2](960378-34-1)

Safety Data

• Hazardous Substances Data: 960378-34-1(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 10099-66-8 lutetium(III) chloride 
• 591-51-5 phenyllithium 

Relevant articles and documents

Cationic aryl complexes of the rare-earth metals

Neutral rare-earth metal tri(aryl) complexes [Ln(C6H 4-P-R)3(THF)2] (Ln = Lu, Sc; R = H, Me, Et), synthesized by reacting anhydrous metal trichloride with 3 equiv of the corresponding aryllithium, react with 1 or 2 equiv of [NR′3H] [BPh4] (R′ = Et; R′3 = PhMe2) to yield monocationic di(aryl) complexes [Ln(C6H4-P-R) 2(THF)4I+[BPh4]- and dicationic mono(aryl) complexes [Ln(C6H4-p-R)(THF) 5]2+[BPh4]-2, respectively. Single-crystal X-ray diffraction studies of the mono- and dicationic compounds [Sc(C6H5)2(THF)4] +[BPh4]- and [Lu(C6H 5)(THF)5]2+[BPh4]2 - show distorted octahedral coordination geometry around the metal center in the cation. Kinetic studies for the reaction of the dicationic complex [Lu(C6H4-p-Me)(THF)5]2+[BPh 4]2- with pyridine suggest competition between C-H bond activation and insertion reactions.