96093-88-8Relevant academic research and scientific papers
ASYMMETRIC DIELS - ALDER REACTIONS WITH α-CHLORONITROSO COMPOUNDS - I. APPLICATION OF α-CHLORONITROSO EPIANDROSTERONE IN SYNTHESIS
Sabuni, Mahmud,Kresze, Guenter,Braun, Heinz
, p. 5377 - 5380 (1984)
The Diels - Alder reaction of 1,3-cyclohexadiene (9) with the enantiomerically pure α-chloronitroso compound 8, synthesized from epiandrosterone (7a), gives the adduct 10a with 1-(R),4-(S) configuration in 69 percent chemical yield and >=95 percent enantiomeric excess.
