ASYMMETRIC DIELS - ALDER REACTIONS WITH α-CHLORONITROSO COMPOUNDS - I. APPLICATION OF α-CHLORONITROSO EPIANDROSTERONE IN SYNTHESIS

DOI: 10.1016/S0040-4039(01)91288-2

Source and publish data:

Tetrahedron Letters p. 5377 - 5380 (1984)

Update date:2022-09-26

Topics:

Authors:

Sabuni, Mahmud

Kresze, Guenter

Braun, Heinz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)91288-2

The Diels - Alder reaction of 1,3-cyclohexadiene (9) with the enantiomerically pure α-chloronitroso compound 8, synthesized from epiandrosterone (7a), gives the adduct 10a with 1-(R),4-(S) configuration in 69 percent chemical yield and >=95 percent enantiomeric excess.

Full text of DOI:10.1016/S0040-4039(01)91288-2

Products guided by the article

Product name:N-((1S,4R)-4-Hydroxy-cyclohex-2-enyl)-benzamide

Cas No:96093-88-8

R&D Labs maybe for 96093-88-8

Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China

Relevant to this article

Synthesis of the 1,2,3,4-Tetrahydropyrazino<2,1-a>isoindol-6(2H)-one Ring System

Doi:10.1021/jo00344a026
(1982)
DERIVATIVES OF S-α- AND -β-D-HEXOPYRANOSYL THIOPHOSPHATES

Doi:10.1016/S0008-6215(00)84696-0
(1981)
Iron-catalyzed regio- and stereoselective conjugate addition of aryl-grignard reagents to α,β,γ,δ-unsaturated sulfones and its synthetic application

Doi:10.1002/adsc.201201124
(2013)
ANOMALOUS METALATION BEHAVIOR IN 1,3-OXAZOLES. ALKYLATION OF 2-METHYL-4-CARBOXYOXAZOLES VIA THE CORNFORTH INTERMEDIATE

Doi:10.1016/S0040-4039(01)81853-0
(1981)
An Odorless Preparative Method of Sulfides and Thiocarboxylic S-Esters Using 3-(Alkylthio)-1,2-benzisothiazole 1,1-Dioxide

Doi:10.1246/bcsj.56.949
(1983)
Preparation of 2- And 4-(2-alkylcarbamoyl-1-methylvinyl)-7-alkyloxybenzo[b]furans having potent antagonistic activity against human leukotriene B₄ BLT₁ and/or BLT₂ receptors

Doi:10.1039/b411286e
(2004)

Article Doi