ASYMMETRIC DIELS - ALDER REACTIONS WITH α-CHLORONITROSO COMPOUNDS - I. APPLICATION OF α-CHLORONITROSO EPIANDROSTERONE IN SYNTHESIS

DOI: 10.1016/S0040-4039(01)91288-2

Source and publish data:

Tetrahedron Letters p. 5377 - 5380 (1984)

Update date:2022-09-26

Topics:

Authors:

Sabuni, Mahmud

Kresze, Guenter

Braun, Heinz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)91288-2

The Diels - Alder reaction of 1,3-cyclohexadiene (9) with the enantiomerically pure α-chloronitroso compound 8, synthesized from epiandrosterone (7a), gives the adduct 10a with 1-(R),4-(S) configuration in 69 percent chemical yield and >=95 percent enantiomeric excess.

Full text of DOI:10.1016/S0040-4039(01)91288-2

Products guided by the article

Product name:N-((1S,4R)-4-Hydroxy-cyclohex-2-enyl)-benzamide

Cas No:96093-88-8

R&D Labs maybe for 96093-88-8

Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province

Relevant to this article

Synthesis of the 1,2,3,4-Tetrahydropyrazino<2,1-a>isoindol-6(2H)-one Ring System

Doi:10.1021/jo00344a026
(1982)
DERIVATIVES OF S-α- AND -β-D-HEXOPYRANOSYL THIOPHOSPHATES

Doi:10.1016/S0008-6215(00)84696-0
(1981)
Iron-catalyzed regio- and stereoselective conjugate addition of aryl-grignard reagents to α,β,γ,δ-unsaturated sulfones and its synthetic application

Doi:10.1002/adsc.201201124
(2013)
ANOMALOUS METALATION BEHAVIOR IN 1,3-OXAZOLES. ALKYLATION OF 2-METHYL-4-CARBOXYOXAZOLES VIA THE CORNFORTH INTERMEDIATE

Doi:10.1016/S0040-4039(01)81853-0
(1981)
An Odorless Preparative Method of Sulfides and Thiocarboxylic S-Esters Using 3-(Alkylthio)-1,2-benzisothiazole 1,1-Dioxide

Doi:10.1246/bcsj.56.949
(1983)
Preparation of 2- And 4-(2-alkylcarbamoyl-1-methylvinyl)-7-alkyloxybenzo[b]furans having potent antagonistic activity against human leukotriene B₄ BLT₁ and/or BLT₂ receptors

Doi:10.1039/b411286e
(2004)

Article Doi