96150-90-2Relevant academic research and scientific papers
The Convergent Synthesis of Polyether Ionophore Antibiotics: The Synthesis of the Monensin Bis(tetrahydrofuran) via the Claisen Rearrangement of an Ester Enolate with a β-Leaving Group
Ireland, Robert E.,Norbeck, Daniel W.
, p. 3279 - 3285 (2007/10/02)
The monensin bis(tetrahydrofuran) 25, a versatile intermediate for the synthesis of polyether ionophore antibiotics, is prepared from D-xylose and D-mannose.In the key step, in situ silylation of an ester enolate with a β-leaving group allows the tetrahyd
