96178-31-3

Basic information

• Product Name: DIBENZYL (ALPHA-ANILINOBENZYL)-PHOSPHONATE
• Synonyms: DIBENZYL (ALPHA-ANILINOBENZYL)-PHOSPHONATE;N-[bis(phenylmethoxy)phosphoryl-phenylmethyl]aniline
• CAS NO: 96178-31-3
• Molecular Formula: C₂₇H₂₆NO₃P
• Molecular Weight: 443.47
• Mol File: 96178-31-3.mol
• Article Data: 1

Chemical Properties

• Melting Point: 109-110 °C
• Boiling Point: 621.5±55.0 °C(Predicted)
• Appearance: /
• Density: 1.226±0.06 g/cm3(Predicted)
• PKA: 1.72±0.50(Predicted)
• CAS DataBase Reference: DIBENZYL (ALPHA-ANILINOBENZYL)-PHOSPHONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIBENZYL (ALPHA-ANILINOBENZYL)-PHOSPHONATE(96178-31-3)
• EPA Substance Registry System: DIBENZYL (ALPHA-ANILINOBENZYL)-PHOSPHONATE(96178-31-3)

Safety Data

• Hazardous Substances Data: 96178-31-3(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 62-53-3 aniline 
• 538-60-3 dibenzyl hydrogen phosphite 
• 538-51-2 benzylidene phenylamine 
• 17176-77-1 Dibenzyl phosphite 

Relevant articles and documents

The synthesis of α-aryl-α-aminophosphonates and α-aryl-α-aminophosphine oxides by the microwave-assisted Pudovik reaction

A family of α-aryl-α-aminophosphonates and α-aryl-α-aminophosphine oxides was synthesized by the microwave-assisted solvent-free addition of dialkyl phosphites and diphenylphosphine oxide, respectively, to imines formed from benzaldehyde derivatives and primary amines. After optimization, the reactivity was mapped, and the fine mechanism was evaluated by DFT calculations. Two α-aminophosphonates were subjected to an X-ray study revealing a racemic dimer formation made through a N-H?O=P intermolecular hydrogen bridges pair.