96182-90-0Relevant articles and documents
Zn(II) Complex Catalyzed Coupling Aquathermolysis of Water-Heavy Oil-Methanol at Low Temperature
Chen, Gang,Yuan, Weihua,Yan, Jiao,Meng, Mei,Guo, Zheng,Gu, Xuefan,Zhang, Jie,Qu, Chengtun,Song, Hua,Jeje, Ayodeji
, p. 197 - 202 (2018)
A Zn(II) coordination complex was synthesized, characterized, and used for catalytic aquathermolysis of heavy oil at low temperatures for the first time. The effects of water content and catalyst concentration on aquathermolysis were investigated. And then a tri-component coupling aquathermolysis of waterheavy oil-methanol was designed and the reaction conditions were investigated. With the catalyst and methanol, the reaction occurred at temperatures as low as 180°C. The viscosity of the product was also substantially reduced from around 24 400 to 6420 mPa s by the decomposition of the large hydrocarbon molecules.
Reaction on a solid surface - A simple, economical, and efficient Mannich reaction of azacrown ethers over graphite
Sharghi, Hashem,Khalifeh, Reza
, p. 426 - 434 (2008/09/20)
Graphite brings about a rapid Mannich reaction with a range of activated and unactivated phenolic compounds such as p-cresol and p-nitrophenol. The reactions are carried out with azacrown ether and paraformaldehyde in solvent-free conditions at 100 °C for 20-30 min. The graphite powder can be reused up to three times after simple washing with acetone.