96201-10-4

Basic information

• Product Name: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(phenylmethyl)-
• CAS NO: 96201-10-4
• Molecular Formula: C13H23NSi
• Molecular Weight: 221.418
• Mol File: 96201-10-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(phenylmethyl)-(96201-10-4)
• EPA Substance Registry System: Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(phenylmethyl)-(96201-10-4)

Safety Data

• Hazardous Substances Data: 96201-10-4(Hazardous Substances Data)

Upstream product

• 29681-57-0 tert-butyldimethylsilane 
• 100-46-9 benzylamine 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 172095-73-7 N-tert-butyldimethylsilylbenzylimine 

Relevant articles and documents

A Tunable and Enantioselective Hetero-Diels–Alder Reaction Provides Access to Distinct Piperidinoyl Spirooxindoles

The active complexes of chiral N,N′-dioxide ligands with dysprosium and magnesium salts catalyze the hetero-Diels–Alder reaction between 2-aza-3-silyloxy-butadienes and alkylidene oxindoles to selectively form 3,3′- and 3,4′-piperidinoyl spirooxindoles, respectively, in very high yields and with excellent enantioselectivities. The exo-selective asymmetric cycloaddition successfully regaled the construction of sp3-rich and highly substituted natural-product-based spirooxindoles supporting many chiral centers, including contiguous all-carbon quaternary centers.

Silicon-assisted synthesis of β-lactams

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