96202-73-2

Upstream product

• 96202-71-0 (Z)-1-(1,3-dioxolan-2-yl)-2-nitronon-6-en-3-ol 
• 82891-99-4 ethylene ketal of 3-nitropropanal 
• 18742-02-4 2-bromo-2-(2-ethyl)dioxolane 
• 96202-72-1 (Z)-1-(1,3-dioxolan-2-yl)-2-nitronon-6-en-3-one 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 96202-74-3 (Z)-1-(1,3-dioxolan-2-yl)-non-6-en-3-one p-toluenesulfonylhydrazone 
• 41031-87-2 (Z)-4-oxodec-7-enal 
• 41031-88-3 (Z)-2-(2-pentenyl)-2-cyclopenten-1-one 

Relevant academic research and scientific papers

2-(2-NITROETHYL)-1,3-DIOXOLANE AS REAGENT FOR 3-OXOPROPYL ANION SYNTHON: A NEW ROUTE TO JASMONOID AND PROSTAGLANDIN INTERMEDIATES

2-(2-Nitroethyl)-1,3-dioxolane is a versatile reagent for 3-oxopropyl anion synthon.New methodology, based on nitroaldol condensation, oxidation and direct or indirect denitration sequence is developed for the conversion of 2-(2-nitroethyl)-1,3-dioxolane into (Z)-1,4-dioxodec-7-ene, (Z)-2-(2-pentenyl)-2-cyclopenten-1-one, methyl 9,12-dioxododecanoate and methyl 7-(5-oxocyclopentenyl)heptanoate, which are popular intermediates for syntheses of (Z)-jasmonoids and prostaglandins.