96220-77-8Relevant academic research and scientific papers
Aluminum chloride catalyzed hydrosilylation of cyclopropanes with chlorodimethylsilane
Nagahara, Shigeru,Yamakawa, Takashi,Yamamoto, Hisashi
, p. 5057 - 5060 (2007/10/03)
Aluminum chloride can be utilized as an active catalyst for the highly regioselective hydrosilylation of 1-alkyl, 1-aryl, 1,1-dialkyl, and cyclic cyclopropanes with chlorodimethylsilane in hexane at room temperature.
246. Monofunctional (Dimethylamino)silane as Silylating Agent
Szabo, Katalin,Le Ha, Ngoc,Schneider, Philippe,Zeltner, Peter,sz. Kovacs, Ervin
, p. 2128 - 2142 (2007/10/02)
The reaction of triorganyl(dimethylamino)silanes with surface-hydrated silicon dioxide has been studied.These silylating agents are easy to prepare from the corresponding chloro or bromosilanes with dimethylamine.The resulting products are thermally stable and relatively volatile.Reaction with surface-hydrated silicon-dioxide preparations at a50-250 deg C for 170 h yields a dense grafted layer.However, with (dimethylamino)silanes having strongly polar substituents, a retreatment of the surface-modified silica seems to be necessary in order to attain maximum coverage.
