96236-35-0

Upstream product

• 138481-64-8 Acetic acid (2R,3S,4S)-2,3,4-tris-benzyloxy-5-oxo-pentyl ester 
• 138481-57-9 Acetic acid (2R,3R,4R)-2,3,4-tris-benzyloxy-5-hydroxy-pentyl ester 
• 2405-69-8 2,3,4-tri-O-benzyl-D-arabinitol 
• 96236-33-8 (2S,3S,4R)-1,1-Bis-ethylsulfanyl-5-trityloxy-pentane-2,3,4-triol 
• 100-39-0 benzyl bromide 
• 6838-08-0 (2R,3S,4S)-5,5-bis(ethylthio)pentane-1,2,3,4-tetraol 
• 96236-34-9 C₄₉H₅₂O₄S₂ 

Downstream Products

• 94898-35-8 (3R,4S,5R)-2-<(bismethoxycarbonyl)methyl>-3,4,5-tribenzyloxytetrahydropyran 
• 96290-92-5 (2S,3R,4S,5R)-dimethyl 2-hydroxy-2,4,5-tribenzyloxycyclohexene-1,1-dicarboxylate 
• 96290-91-4 (2S,3R,4S,5R)-dimethyl 2-hydroxy-2,4,5-tribenzyloxycyclohexene-1,1-dicarboxylate 
• 96236-37-2 2,3,4-tri-O-benzyl-5-O-mesyl-D-lyxose 
• 96290-95-8 dimethyl (2R,3R,4S,5R)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 96290-94-7 dimethyl (2S,3R,4S,5R)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 96236-36-1 Methanesulfonic acid (2S,3S,4S)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyl ester 

Relevant academic research and scientific papers

Biocatalytic Desymmetrizations of Pentitol Derivatives

Several acylations of pentitol derivatives mediated by Candida cylindracea have been shown to be enantio-, or diastereo-, group selective; a pattern emerges from the selectivities of these reactions which may have some predictive value.Key words: acylation; catalysis; Candida cylindracea lipase; kinetic amplification of diastereomeric excess

SYNTHESIS OF METHYL (-)-SHIKIMATE FROM D-XYLOSE

Natural methyl (-)-shikimate has been synthesized from D-lyxose, employing a double carbon-carbon bond formation of 2,3,4-tri-O-benzyl-5-O-mesyl-D-lyxose with a dianion of dimethyl malonate as a key reaction.