96286-46-3

Basic information

• Product Name: 2H-1,3-Oxazine, 3-ethyltetrahydro-5-[(4-nitrophenyl)methylene]-, (E)-
• CAS NO: 96286-46-3
• Molecular Formula: C13H16N2O3
• Molecular Weight: 248.282
• Mol File: 96286-46-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2H-1,3-Oxazine, 3-ethyltetrahydro-5-[(4-nitrophenyl)methylene]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1,3-Oxazine, 3-ethyltetrahydro-5-[(4-nitrophenyl)methylene]-, (E)-(96286-46-3)
• EPA Substance Registry System: 2H-1,3-Oxazine, 3-ethyltetrahydro-5-[(4-nitrophenyl)methylene]-, (E)-(96286-46-3)

Safety Data

• Hazardous Substances Data: 96286-46-3(Hazardous Substances Data)

Upstream product

• 100-14-1 4-nitrobenzyl chloride 
• 96286-41-8 ethyl-3 hydroxymethyl-5 nitro-5 tetrahydrooxazine-1,3 
• 96286-44-1 3-ethyl-5-p-nitrobenzyl-5-nitrotetrahydro-1,3-oxazine 

Relevant articles and documents

SYNTHESIS OF NEW 5-NITROTETRAHYDRO-1,3-0XAZINE DERIVATIVES VIA ELECTRON-TRANSFER REACTIONS

5-Nitrotetrahydro-1,3-oxazine salts are found to be useful nucleophiles for SRN1 reactions with p-nitrobenzyl chloride, 2,2-dinitropropane and 1-methyl-2-chloromethyl-5-nitroimidazole.From C-alkylation products, base promoted nitrous acid elimination and electron-transfer elimination of the two nitro groups afford new tetrahydro-1,3-oxazines with respectively a tri- and tetrasubstituted double bond at the 5 position.These new tetrahydro-1,3-oxazines can be hydrolysed to the corresponding ethylenic aminoalcohols by heating with hydrochloric acid.