96302-83-9

Upstream product

• 96302-65-7 (E)-5-diphenylphosphinoyl-4-methyldec-2-en-4-ol 
• 96302-92-0 (E)-5-diphenylphosphinoyl-4-methyldec-3-en-2-one 
• 96302-73-7 Acetic acid (E)-4-(diphenyl-phosphinoyl)-1,3-dimethyl-non-2-enyl ester 
• 19259-70-2 n-hexyldiphenylphosphine oxide 
• 3102-33-8 trans-3-penten-2-one 
• 96302-83-9 (E)-5-diphenylphosphinoyl-4-methyldec-3-en-2-ol 

Downstream Products

• 99381-88-1 (S)-1-{(2S,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-3-methyl-oxiranyl}-ethanol 
• 99381-88-1 (S)-1-{(2R,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-3-methyl-oxiranyl}-ethanol 
• 96302-83-9 (2RS,5SR;E)-5-diphenylphosphinoyl-4-methyldec-3-en-2-ol 
• 96302-83-9 (2RS,5RS)-5-diphenylphosphinoyl-4-methyldec-3-en-2-ol 
• 4559-70-0 Diphenylphosphine oxide 
• 96302-92-0 (E)-5-diphenylphosphinoyl-4-methyldec-3-en-2-one 

Relevant academic research and scientific papers

Stereochemical Control (E/Z and syn/anti) by the Diphenylphosphinoyl Group in the Synthesis of Allylic Alcohols by Allylic Rearrangement and by 1,4-Diastereoselective Reduction of Enones

Allylic rearrangement of substituted 2-hydroxyalk-3-en-1-yl(diphenyl)phosphine oxides to 4-hydroxyalk-2-en-1-yl(diphenyl)phosphine oxides can be performed with total regio- and reasonable stereochemical control.Alternatively, the reduction of substituted

TRANSPOSITION OF ALLYLIC ALCOHOLS CONTROLLED BY THE Ph2PO GROUP: REAGENTS FOR α-HYDROXY-DIENE SYNTHESIS BY THE HORNER-WITTIG REACTION

4-Hydroxy-2-alkenyldiphenylphosphine oxides, prepared by a phosphorus-controlled allylic rearrangement, give dianions and hence α-hydroxydienes (substitued penta-2,4-dienols) by the Horner-Wittig reaction.

STEREOCONTROLLED SYNTHESIS OF δ-HYDROXY ALLYLIC PHOSPHINE OXIDES BY ALLYLIC ESTER TRANSPOSITION

The title compounds (3) were synthesised by stereospecific rearrangement, controlled by the Ph2PO group, from single isomers of the Horner-Wittig adducts (1).